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ACE Food & Beverage Applications Guide-Hichrom

250 Pesticide Screen using LC-MS/MS Application #AN3060 Page 4 of 4 Analyte Rt Adduct Precurso r Ion m/z Quant Ion m/z Conf Ion mz Pirimicarb 4.24 M+H+ 239.2 182.1 72.0 Pirimicarb Desmethyl 2.71 M+H+ 225.1 168.2 72.1 Pirimiphos Methyl 7.34 M+H+ 306.1 164.2 108.1 Prallethrin 7.69 M+H+ 301.2 133.0 151.2 Prochloraz 7.39 M+H+ 376.0 308.1 70.1 Profoxydim 7.71, 9.00 M+H+ 466.2 280.0 180.0 Promecarb 5.88 M+H+ 208.1 109.0 151.1 Propamocarb 1.41 M+H+ 189.1 102.0 144.0 Propaquizafop 8.21 M+H+ 444.1 299.2 371.2 Propargite 8.74 M+NH4+ 368.2 231.2 175.1 Propetamphos 6.13 M+H+ 282.1 138.1 156.1 Propoxur (S) 3.69 M+H+ 210.1 168.2 111.1 Prosulfuron 5.29 M+H+ 420.1 167.1 141.1 Pymetrozine 1.44 M+H+ 218.1 105.1 78.1 Pyraclostrobin 7.30 M+H+ 388.1 163.1 194.1 Pyraflufen Ethyl 7.13 M+H+ 413.0 339.0 253.1 Pyrazophos 7.31 M+H+ 374.1 222.2 194.1 Pyridaben 9.22 M+H+ 365.1 309.0 147.1 Pyridalyl 10.21 M+2+H+ 492.0 110.9 164.0 Pyrimethanil 5.45 M+H+ 200.1 107.1 168.1 Pyriproxyfen 8.39 M+H+ 322.1 96.0 227.1 Quinalphos 6.78 M+H+ 299.1 163.1 147.1 Quinoxyfen 8.50 M+H+ 308.0 197.1 214.1 Quizalofop Ethyl 8.01 M+H+ 373.1 299.2 255.1 Resmethrin 9.40 M+H+ 339.2 128.1 171.1 Rimsulfuron 3.94 M+H+ 432.1 182.1 139.0 Rotenone 6.71 M+H+ 395.2 213.2 192.1 Saflufenacil 5.32 M+H+ 501.1 349.1 198.0 Sedaxane 6.20, 6.54 M+H+ 332.2 159.0 139.0 Sethoxydim 8.03 M+H+ 328.2 178.0 220.1 Simazine 3.66 M+H+ 202.1 104.1 132.1 Spinetoram 8.14 M+H+ 748.5 142.1 203.1 Spinosad A 7.69 M+H+ 732.5 142.1 98.0 Spinosad D 8.10 M+H+ 746.5 142.1 98.0 Spirodiclofen 8.91 M+H+ 411.1 313.1 71.1 Analyte Rt Adduct Precursor Ion m/z Quant Ion m/z Conf Ion mz Spiromesifen 8.66 M+NH4+ 388.1 273.1 187.0 Spiromesifen Alcohol 5.01 M+H+ 273.2 187.1 179.1 Spirotetramat 6.38 M+H+ 374.2 302.3 216.2 Spiroxamine 5.95 M+H+ 298.3 144.2 100.2 Sulfoxaflor 2.39 M+NH4+ 295.2 174.1 154.1 Sulprofos 8.56 M+H+ 323.0 219.1 139.1 TCMTB 5.48 M+H+ 239.0 180.0 136.0 Tebufenozide 6.78 M+H+ 353.2 133.0 104.8 Tebufenpyrad 8.19 M+H+ 334.2 117.1 145.1 Tebuthiuron 3.89 M+H+ 229.1 172.0 116.0 Tepraloxydim 4.10, 6.19 M+H+ 342.2 250.1 166.1 Terbufos Sulfone 5.46 M+H+ 321.0 115.0 143.0 Terbufos Sulfoxide 5.49 M+H+ 305.1 97.0 187.0 Terbuthylazine 5.71 M+H+ 230.1 174.1 104.1 Tetrachlorvinphos 6.86 M+2+H+ 366.9 127.1 206.0 Tetramethrin 7.91, 8.10 M+H+ 332.2 164.1 135.1 Thiabendazole 2.48 M+H+ 202.0 175.0 131.1 Thiacloprid 2.55 M+H+ 253.0 126.1 99.1 Thiamethoxam 1.65 M+H+ 292.0 211.1 181.1 Thifensulfuron Methyl 3.28 M+H+ 388.0 167.1 205.0 Thiobencarb 7.46 M+H+ 258.1 125.0 89.0 Thiodicarb 4.34 M+H+ 355.1 163.2 88.1 Thionazin 4.74 M+H+ 249.1 193.1 97.0 Topramezone 1.63 M+H+ 364.1 334.1 125.1 Triadimefon 6.07 M+H+ 294.1 197.0 225.0 Triadimenol 6.25 M+H+ 296.1 70.2 99.0 Triazophos 6.19 M+H+ 314.1 162.1 119.1 Tribenuron Methyl 4.59 M+H+ 396.1 155.1 181.1 Trichlorfon 2.26 M+H+ 256.9 109.0 221.0 Tricyclazole 2.80 M+H+ 190.0 163.1 136.1 Trifloxystrobin 7.78 M+H+ 409.1 186.2 206.2 Triflumizole 7.87 M+H+ 346.1 278.0 73.0 Triforine 5.23 M+2+H+ 434.9 213.0 98.2 Zoxamide 7.09 M+H+ 336.0 187.0 159.0 59


ACE Food & Beverage Applications Guide-Hichrom
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